2024 – Present
Decarbonizing Steam-Methane Reforming: Enhancing Activity through Joule Heating of a Ni/ZrO2-Coated FeCrAl Coil
Ledesma, E. B., Idamakanti, M., Bollini, P., Harold, M. P.*, Ratnakar, R. R.,
ChemCatChem 16(8) (2024), p.e202301110
Electrified Catalysts for Endothermic Chemical Processes: Materials Needs, Advances, and Challenges
Idamakanti, M., Ledesma, E. B., Ratnakar, R., Harold, M. P., Balakotaiah, V., Bollini, P.*, ACS Eng. Au 4 (2024) 71−90
Kinetic Requirements for Selectivity Enhancement During Forced Dynamic Operation of the Oxidative Dehydrogenation of Ethane
Morales, A., Harold, M. P.*, Bollini, P.*, ACS Catal. 14 (2024) 7877-7892
Recommendations for Improving Rigor and Reproducibility in Site Specific Characterization
Wrasman, C. J., Bell, A. T., Chandler, B. D., Harris, J. W., Kwon, S., Ball, M. R., Krishna, S. H., Khatib, S. J., Bollini, P., Román-Leshkov, Y., Weber, R. S., Lercher, J. A., Liu, D., Resasco, D. E., Bates, J.S., Hall, J. N., Lebrón-Rodríguez, E. A., Herrera, L. P., Notestein, J. M., Schaidle, J. A.*, Catal. 433 (2024) 115451 – 115463.
Can the Rate of a Catalytic Turnover Be Altered by Ligands in the Absence of Direct Binding Interactions?
Hall, J. N., Vicchio, S. P., Kropf, J., Delferro, M, Bollini, P.*, Am Chem. Soc. 146(17) (2024) 12113–12129
2023
Active Sites, Kinetics, and Inhibiting Species in the Catalytic Dehydration of Methanol over MIL-100(Cr)
Li, M., Hall, J. N., Bollini, P.*, Catal. Sci. Technol. 13 (2023), 1735-174
On the Utility of Ce3+ Spin-Orbit Transitions in the Interpretation of Rate Data in Ceria Catalysis: Theory, Validation, and Application
Afrin, S., Bollini, P.*,
J. Phys. Chem. C, 127 (2023) 234-247
Functional Wood for Carbon Dioxide Capture
Roy, S., Philip, F. A., Oliveira, E. F., Singh, G., Joseph, S., Yadav, R. M., Adumbumkulath, A., Hassan, S., Khater, A., Wu, X., Bollini, P., Vinu, A., Shimizu, G., Ajayan, P. M., Kibria, M. G., Rahman, M. M., Cell Rep. Phys. Sci. ,(2023)
Carbon Dioxide Sorbent from Construction and Textile Waste
Savas, P. E., Algozeeb, W. A., Wang, Z., Kittrell, C., Wu, X., Hall, J. N., Malloy, T. B., Bollini, P.,* Tour, J. M.*, Adv. Sustainable Syst. 2200436 (2023) 1-9
Bifunctional Gas Diffusion Electrode Enables In-situ Capture and Conversion of CO2 from Dilute Streams
Nabil, S. K., Roy, S., Algozeeb, W. A., Al Bari, M. A., Zeraati, A. S., Demingos, P. G., Rao, A., Tran, T. N., Wu, X., Bollini, P., Lin, H., Singh, C. V., Tour, J.M., Ajayan, P. M., Kibria, M. G., Adv. Mater. 2300389 (2023) 1-11.
Scale-up Analysis of the Oxidative Dehydrogenation of Ethane over M1 Phase Catalysts using Autothermal Reactors
Chen, J., Sun, Z., Bollini, P.*, Balakotaiah, V.*, Chem. Eng. Sci. 273 (2023) 118649-118664
Spectroscopic and Reactive Characterization of Mixed-Metal Fe–Cr Trimer Nodes in Metal–Organic Framework MIL-100
Hall, J. N., Bollini, P.*, Chem. Commun. 59 (2023) 4758-4761
Kinetic and X ray Absorption Spectroscopic Analysis of Catalytic Redox Cycles over Highly Uniform Polymetal Oxo Clusters
Hall, J. N., Kropf, J., Delferro, M, Bollini, P.*, ACS Catal. 13 (2023) 5406−5427
Shallow-Bed Reactor Design for the Autothermal Oxidative Dehydrogenation of Ethane over MoVTeNbOx Catalysts
Chen, J., Bollini, P.*, Balakotaiah, V.*, Chem. Eng. J. (2023) 145660-145672
Vision 2050: Reaction Engineering Roadmap
Bollini, P., Diwan, M., Gautam, P., Hartman, R., Hickman, D., Johnson, M., Kawase, M., Neurock, M., Patience, G., Stottlemyer, A., Vlachos, D., Wilhite, B., ACS Eng. (2023) 364-390 Au
Dynamic Rate Analysis for Low Frequency Operation of Chemical Reactors
Morales, A., Bollini, P., Harold, M. P.*, Chem. Eng. J. 475 (2023)146103 146118
2019-2022
On the Utility of Ce3+ Spin-Orbit Transitions in the Interpretation of Rate Data in Ceria Catalysis: Theory, Validation, and Application
Afrin, S., Bollini, P.
Under revision (J. Phys. Chem. C)
Carbonate Dimorphism, and the Reinterpretation of Rates of Lattice and Excess Oxygen Driven Catalytic Cycles
Zhao, X., Ning, Q., Grabow, L. C., Rimer, J. D., Bollini, P.*, J. Catal. 416 (2022) 423-438
Beyond Upper Bound Estimates of Active Site Densities in Heterogeneous Catalysis: A note on the Critical Role of Titrant Pressure
Afrin, S., Bollini, P.*, J. Catal. 413 (2022) 76-80
A Global Kinetic Model for the Oxidative Dehydrogenation of Ethane over Mixed Metal Oxide Catalysts at Supra-Ambient Pressures
Chen, J., Sun, Z., Balakotaiah, V., Bollini, P.
Chem. Eng. J. 445 (2022) 136605-136621.
Role of Metal Identity and Speciation in the Low-Temperature Oxidation of Methane over Tri-Metal Oxo Clusters
Hall, J.N., Bollini, P.
AIChE J. 26 (2022) 1-13.
Technological Options for Direct Air Capture: A Comparative Process Engineering Review
Wu, X., Krishnamoorti, R., Bollini, P.
Annu. Rev. Chem. Biomol. Eng. 13 (2022) 279-300.
Plastic Waste Product Captures Carbon Dioxide in Nanometer Pores
Algozeeb, W. A., Savas, P. E., Yuan, Z., Wang, Z., Kittrell, C., Hall, J. N., Chen, W., Bollini, P., Tour, J. M.
ACS Nano 16 (2022) 7284-7290.
Tuning CO2 Binding in Metal–Organic Framework Materials by Varying Metal Identity and Oxidation State
Li, M., Hall, J. N., Fleming, K., Bollini, P.
Energy Fuels 36 (2022) 5816-5824.
Light Alkane Oxidation over Well-Defined Active Sites in Metal–Organic Framework Materials
Hall, J.N., Li, M.L., Bollini, P.
Catal. Sci. Technol. 12 (2022) 418-435.
Synthesis, Structure, and Catalytic Properties of Faceted Oxide Crystals
Zhao, X., Susman, M.D., Rimer, J.D., Bollini, P.
ChemCatChem 13 (2021) 6-27.
Tuning Selectivity in Nickel Oxide-Catalyzed Oxidative Dehydrogenation of Ethane through Control over Non-Stoichiometric Oxygen Density
Zhao, X., Susman, M.D., Rimer, J.D., Bollini, P.
Catal. Sci. Technol. 11 (2021) 531-541.
A Transient Kinetic Analysis of the Evolution of a Reducible Metal Oxide Towards Catalyzing Non-Oxidative Alkanol Dehydrogenation
Afrin, S., Bollini, P.
J. Catal. 393 (2021) 290-302.
Oxidative Dehydrogenation of Ethane over Mixed Metal Oxide Catalysts: Autothermal or Cooled Tubular Reactor Design?
Chen, J., Bollini, P., Balakotaiah, V.
AIChE J. 67 (2021) 1-13.
Low-Temperature, Ambient Pressure Oxidation of Methane to Methanol Over Every Tri-Iron Node in a Metal-Organic Framework Material
Hall, J.N., Bollini, P.
Chem. Eur. J. 26 (2020) 16639-16643.
Enabling Access to Reduced Open-Metal Sites in Metal-Organic Framework Materials through Choice of Anion Identity: The Case of MIL-100(Cr)
Hall, J.N., Bollini, P.
ACS Materials Lett. 2 (2020) 838-844.
Synthesis of NiO Crystals Exposing Stable High-Index Facets
Susman, M.D., Pham, H.N., Zhao, X., West, D., Chinta, S., Bollini, P., Datye, A.K., Rimer, J.D.
Angew. Chem. Int. Ed. 59 (2020) 15119-15123.
Metal-Organic Framework MIL-100 Catalyzed Acetalization of Benzaldehyde with Methanol: Lewis or Brønsted Acid Catalysis?
Hall, J.N., Bollini, P.
ACS Catalysis 10 (2020) 3750-3763.
Quantification of Open-Metal Sites in Metal−Organic Frameworks Using Irreversible Water Adsorption
Hall, J.N., Bollini, P.
Langmuir 36 (2020) 1345-1356.
Cerium Oxide Catalyzes the Selective Vapor Phase Hydrodeoxygenation of Anisole to Benzene at Ambient Pressures of Hydrogen
Afrin, S., Bollini, P.
Ind. Eng. Chem. Res. 58 (2019) 14603-14607.
Structure, Characterization, and Catalytic Properties of Open-Metal Sites in Metal-Organic Framework Materials
Hall, J.N., Bollini, P.
React. Chem. Eng. 4 (2019) 207-222.
Graduate and Postdoctoral Work
Mechanistic Role of Water in HSSZ-13 Catalyzed Methanol-to-Olefins Conversion
Bollini, P., Chen, T. T., Neurock, M., Bhan, A.
Catal. Sci. Technol. 9 (2019) 4374-4383.
Improving HSAPO‐34 Methanol‐to‐Olefin Turnover Capacity by Seeding the Hydrocarbon Pool
Bollini, P., Bhan, A.,
ChemPhysChem 19 (2018) 479-483.
Deactivation Mechanisms in methanol-to-hydrocarbons chemistry
Bollini, P., Bhan, A.
Catalysis 30 (2018) 146-156.
Important roles of enthalpic and entropic contributions to CO2 capture from flue gas and ambient air using mesoporous silica grafted amines
Alkhabbaz, M. A., Bollini, P., Jones, C. W.
J. Am. Chem. Soc. 136 (2014) 13170-13173.
Dynamics of CO2 adsorption onto Amine Adsorbents. 1. Impact of Heat Effects
Bollini, P., Brunelli, N., Didas, S., Jones, C. W.
Ind. Eng. Chem. Res. 51 (2012) 15145-15152.
Dynamics of CO2 Adsorption onto Amine Adsorbents. 2. Insights into Adsorbent Design
Bollini, P., Brunelli, N., Didas, S., Jones, C. W.
Ind. Eng. Chem. Res. 51 (2012) 15153-15162.
Enhanced CO2 Adsorption over Polymeric Amines Supported on Heteroatom-incorporated SBA-15 Silica: Impact of Heteroatom Type and Loading
Kuwahara, Y., Kang, D., Copeland, J., Bollini, P., Sievers, C., Kamegawa, T., Yamashita, H., Jones, C. W.
E Chem. Eur. J. 18 (2012) 16649-16664.
Dramatic Enhancement of CO2 Uptake by Poly(ethyleneimine) Using Zirconosilicate Supports
Kuwahara, Y., Kang, D., Copeland, J., Brunelli, N., Didas, S., Bollini, P., Sievers, C., Kamegawa, T., Yamashita, H., Jones, C. W.
J. Am. Chem. Soc. 134 (2012) 10757-10760.
Effect of Support Structure on CO2 Adsorption Properties of Pore-Expanded Hyperbranched Aminosilicas
Drese, J., Choi, S., Didas, S., Bollini, P., Gray, M. L., Jones, C. W.
Microporous Mesoporous Mater., 151 (2012) 231-240.
Oxidative Degradation of Aminosilica Adsorbents Relevant to Post-combustion CO2 Capture
Bollini, P., Choi, S., Drese, J., Jones, C. W.
Energy Fuels, 25 (2011) 2416-2425.
Structural Changes of Silica Mesocellular Foam Supported Amine-functionalized CO2 Adsorbents Upon Exposure to Steam
Li, W., Bollini, P., Didas, S., Choi, S., Drese, J., Jones, C. W.
ACS Appl. Mater. Interfaces, 2 (2010) 3363-3372.
Amine-oxide Hybrid Materials for Acid Gas Separations
Bollini, P., Didas, S., Jones, C. W.
J. Mater. Chem., 21 (2011)15100-15120.